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排序方式: 共有263条查询结果,搜索用时 31 毫秒
1.
We tested 5 newly manufactured – prototype – 1013 Ohm resistors in the feedback loop of Faraday cup amplifiers to measure small ion beams by Thermal Ionisation Mass Spectrometry (TIMS). The high Ohmic resistors installed in the TRITON Plus at the VU University Amsterdam theoretically have 10 times lower noise levels relative to the default 1011 Ohm resistors. To investigate the precision and accuracy of analyses using these new amplifiers we measured Sr and Nd isotopes of reference standards at a range of ion currents (3.2 × 10−16 to 1 × 10−12 A, corresponding to intensities of 32 μV to 100 mV on a default 1011 Ohm amplifier) and on small amounts of material (100 and 10 pg). Internal precision and external reproducibility for Sr and Nd isotope ratios are both better when collected on 1013 compared 1012 Ohm resistors and to the default 1011 Ohm resistors. At an 87Sr ion current of 3 × 10−14 A (3 mV on a 1011 Ohm amplifier) the internal precision (2 SE) of 87Sr/86Sr is 5 times better for 1013 Ohm resistors compared to 1011 Ohm resistors. The external reproducibility (2 SD) at this beam intensity is 9 times better. 相似文献
2.
A single crystal of neodymium gallate was investigated by FTIR-spectroscopy in the reststrahlen region between 100–1000 cm−1. The three spectra of the crystal in principal orientations were analyzed by dispersion analysis and the dispersion parameters and the dielectric tensor function were obtained. This allows to properly characterize and quantitatively analyze films of this important substrate material by IR-optical methods. 相似文献
3.
Jian‐Hua Zou Da‐Liang Zhu Fei‐Fei Li Fu‐Song Li He Wu Qiao‐Yun Li Gao‐Wen Yang Ping Zhang Yun‐Xia Miao Jian Xie 《无机化学与普通化学杂志》2014,640(11):2226-2231
Reactions of three tetrazole containing carboxylic acid ligands, namely, Hpztza, Htzpya, and Hpytza [Hpztza = 5‐(2‐pyrazinyl)tetrazole‐2‐acetic acid, Htzpya = 3‐(5‐tetrazolyl)pyridine‐1‐acetic acid, Hpytza = 5‐(3‐pyridyl)tetrazole‐2‐acetic acid] with NdCl3 · 6H2O under hydrothermal conditions, afforded the complexes [Nd(pztza)2(H2O)6] · pztza · 3H2O ( 1 ), [Nd2(tzpya)2(H2O)12]Cl4 · 2H2O ( 2 ), and [Nd(pytza)2Cl(H2O)2] ( 3 ). The compounds were structurally characterized by elemental analysis, IR spectroscopy and single‐crystal X‐ray diffraction. X‐ray diffraction analyses revealed that compound 1 displays a mononuclear structure, 2 shows a dinuclear structure, and 3 features a 1D polymeric chain structure via pytza as linker. Furthermore, the luminescent properties investigated at room temperature in the solid state show that compound 2 has an obvious decrease in its luminescence, when compared to the ligand. 相似文献
4.
Bin Fang Rongxing Shen Cuihong Zhang Huali Yuan Li Yao Guangfeng Wang 《Electroanalysis》2009,21(24):2680-2684
A novel route for the fabrication of neodymium hexacyanoferrate (NdHCF) modified glassy carbon electrodes (GCE) was proposed. The morphological characterization of NdHCF was examined by scanning electron microscopy (SEM) and Fourier transform infrared spectra (FTIR). The performances of the NdHCF/GCE were characterized with cyclic voltammetry and differential pulse voltammograms (DPV). The modified electrode showed excellent electrocatalytic effect and high stability toward the electrochemical oxidation of dopamine (DA) in phosphate buffer solution (pH 5.5) with a diminution of the anodic overpotential of 155 mV. The anodic peak currents increased linearly with the concentration of DA from 5.0×10?7 to 6.0×10?4 M with a detection limit of 1.0×10?8 M (S/N=3). The most important is that the modified electrode could be used for the determination of DA in the presence of an ascorbic acid concentration as large as 100‐fold that of DA. The proposed method was used to determine DA in DA‐hydrochloride injection and showed excellent sensitivity and recovery. The ease of fabrication, high stability, and low cost of the modified electrode are the promising features of the proposed sensor. 相似文献
5.
Neodymium doped Barium Zirconate Titanate (Ba1−xNd2x/3)(Zr0.3Ti0.7)O3 (x = 0.00, 0.02, 0.04, 0.06, 0.08, 0.10) ceramics were prepared using the solid state reaction route. Structural characterizations of the materials were done by using X-ray diffraction and Raman spectroscopy. XRD study suggested that all the compositions were of single phase cubic perovskite structure with space group Pm-3m while Raman spectra revealed that the replacement of the Ba2+ ions by Nd3+ ions significantly reduced the intensity of the Raman active modes and shifted them towards higher energy side. Room temperature optical property was analyzed by photoluminescence spectroscopy, which confirmed formation of shallow defects in the band gap. Photoluminescence property was attributed to the presence of polar [TiO6] distorted clusters in the globally cubic matrix. As a result PL emission spectra of these materials were found to belong to violet–blue regions. Microstructural study of sintered pellets revealed that the grain sizes increase with increase in doping concentration. The temperature dependence of the dielectric properties was investigated in the frequency range 1 kHz to 1 MHz. The broadening in the dielectric constant peak around the phase transition temperature and shifting of the temperature maximum towards higher temperatures with increase in frequency indicated a relaxor type of behavior. 相似文献
6.
Cláudia A. Kodaira Ana Valéria S. Lourenço Maria Cláudia F.C. Felinto Eduardo M.R. Sanchez Francisco J.O. Rios Luiz Antonio O. Nunes Magnus Gidlund Oscar L. Malta Hermi F. Brito 《Journal of luminescence》2011,131(4):727-731
Neodymium based fluorescence presents several advantages in comparison to conventional rare earth or enzyme-substrate based fluorescence emitting sources (e.g.Tb, HRP) . Based on this fact we have herein explored a Nd-based fluoroimmunoassay. We efficiently detected the presence of an oxidized low-density lipoprotein (oxLDL) in human plasma a well-known marker for cardiovascular diseases, which causes around 30% of deaths worldwide. Conventional fluoroimmunoassay uses time-resolved luminescence techniques, with detection in the visible range, to eliminate the fluorescence background from the biological specimens. By using an immunoassay based on functionalized Y2O3:Nd3+ nanoparticles, where the excitation and emission processes in the Nd3+ ion occur in the near-infrared (NIR) region, we have succeeded in eliminating the interferences from the biological fluorescence background, avoiding the use of time-resolved techniques. This yields higher emission intensity from the Nd3+-nanolabels and efficient detection of anti-oxidized low-density lipoproteins (anti-oxLDL) by Y2O3:Nd3+-antibody-antigen conjugation, leading to a novel biolabeling method. 相似文献
7.
V. P. Glazkov B. N. Savenko V. A. Somenkov D. V. Sheptyakov S. Sh. Shilstein 《高压研究》2013,33(3-6):201-207
Abstract The crystal structure of Nd2CuO4 has been studied by neutron diffraction at pressure up to 5 Gpa. The volume compressibility value was determined as 5·6·10?3/Gpa. The decrease of positional parameter of neodymium at high pressure has been observed. This structural change is explained by pressure induced neodymium ions charge increase. 相似文献
8.
《Electroanalysis》2017,29(4):1081-1087
Neodymium (III) oxide (NdOx) was dispersed in chitosan dissolution and deposited on a glassy carbon electrode (chitosan‐NdOx/GCE). The surface properties of the chitosan‐NdOx/GCE were evaluated with FeCN6−3 solution using cyclic voltammetry and electrochemical impedance spectroscopy. The modified electrode was used in the determination of individual dopamine (DP) and ascorbic acid (AA) with square wave adsorptive voltammetry. Under optimal parameters (pH 4.0; accumulation time; tACC 60s and accumulation potential; EACC 0.10 V) for DP and (pH 3,0; tACC 60s and; EACC −0.20 V) for AA, anodic peak currents were proportional to the concentration of DP and AA between 0.90 and 17.0 μmolL−1, with detection limit of 0.079 μmolL−1 for DP and 0.12 μmolL−1 for AA. The sensor was used in the determination of DP and AA in human urine samples and vitamin C tablets with consistent results. The new sensor is easy to develop. In addition, the sensitivity in particular for AA was improved compared with previous work. 相似文献
9.
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